Reactivity pattern of α-bromo & α,α-dibromoderivative of carbonyl compounds
Keywords:
synthesis, -halocarbonyl, versatileAbstract
The synthetic utility of -halocarbonyl compounds is well known for more than a century. They have been widely used as versatile intermediates in organic synthesis. However, there has been considerable recent interest in the development of alternative approaches avoiding the use of these reagents because of their highly lachrymatory properties. In an important development, it has been shown that ,-dihalocarbonyl compounds behave as synthetic equivalent of their corresponding -halocarbonyl compounds.
References
Emmerling, E.; Engler, A. Ber., 1871, 4, 148.
De Kimpe, N.; Verhe, R. The Chemistry of -Haloketones, -Haloaldehydes and
-Haloimines; Patai, S.; Rapporot, Z., Eds.; Interscience: New York, 1988, pp.
-223.
Shunmugasundaram, A.; Rajkumar, M. Indian J. Chem., 1986, 25A, 71.
Srinivasan, C.; Shunmugasundaram, A.; Arumugam, N. Indian J. Chem., 1981, 20B,
Srinivasan, C.; Shunmugasundaram, A.; Arumugam, N. J. Chem. Soc., Perkin
Trans. 2, 1985, 17.
Mohanty, T. R.; Mishra, M. P.; Nayak, P. L. J. Indian Chem. Soc., 1974, 51,
Ananthakrishnander, P.; Prabakaran, T. R. Indian J. Chem., 1996, 35A, 431.
Mishra, S. S.; Behera, G. B.; Nayan, S. Indian J. Chem., 1985, 24A, 771.
Yousaf, T. I.; Lewis, E. S. J. Am. Chem. Soc., 1987, 109, 6137.
Grunwald, W. E.; Jones, H. W. J. Am. Chem. Soc., 1951, 73, 2700.
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