STUDIES ON THE SYNTHESIS AND CHARACTERIZATION OF ZEOLITES AND THEIR APPLICATION AS A CATALYST

Authors

  • Kamlesh Sahu Research Scholar

Keywords:

Zeolites, Catalysis, Hydrothermal Synthesis, Isomerization

Abstract

Because of their wide range of uses in catalysis, adsorption, and ion exchange, zeolites, which belong to the family of microporous aluminosilicate minerals, have garnered a lot of interest in recent years. The synthesis and characterisation of a variety of zeolites, as well as their potential application as catalysts in certain industrial processes, are the primary objectives of this research. Following the hydrothermal synthesis of various zeolite structures, such as ZSM-5, Y-zeolite, and Beta-zeolite, using a variety of templates and raw materials, followed by the structural and chemical characterization of these zeolite structures using techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM), and Fourier-transform infrared spectroscopy (FTIR), the research is being conducted. In order to evaluate the effectiveness and selectivity of the produced zeolites in comparison to traditional catalysts, their catalytic activity is examined in a number of different processes, such as cracking, isomerization, and alkylation. The findings indicate that the particular pore structure, surface area, and acidity of the zeolites have a substantial impact on the catalytic activity of the zeolites. In addition, the catalytic capabilities of zeolites can be further improved by modifying them by ion exchange or impregnation with metal nanoparticles (for example, platinum or lead). After doing the research, the researchers came to the conclusion that zeolites have the potential to be effective catalysts for a variety of chemical transformations that are also kind to the environment. These catalysts are interesting alternatives to traditional catalysts in industrial processes such as the refinement of petrochemicals and the creation of sustainable energy because of their adaptability, the fact that their characteristics may be tuned, and the fact that they can be recycled.

References

Breck D.W. (1974). Zeolites Molecular Sieves, Structure, Chemistry and Use. New York, John Wiley & Sons, 4(1), 771-780.

Chiang A.T. and Chao K.J. (2001). Membranes and Films of Zoelite and Zeolite Like Materials. Journal of Physics and Chemistry of Solids, 62, 1899-1910.

Xu R.W.P., Yu Q., Huo J. and Chen J. (2007). Chemistry of Zeolites and Related Porous Materials: Synthesis and Structure Clementi loop Singapore. John Wiley, 2(3), 679- 687.

Berendsen W.R., Radmer P. and Reuss M. (2006). Pervaporative Seperation of Ethanol from an Alcohol-Ester Quaternary Mixture. Journal of Membrane Science, 280(1- 2), 684-692.

Ivan P. and Michalev M. (2012). Synthesis of zeolite A: A Review. НАУЧНИ ТРУДОВЕ НА РУСЕНСКИЯ УНИВЕРСИТЕТ, 51, 30-35

Georgiev D., Bogdanov B., Angelova K., Markovska I. and Hristov Y. (2009). Synthetic zeolite – Structure, Clasification, Current Trends In Zeolite Synthesis Review. International Science conference, Stara Zagora, Bulgaria, 4-5.

Haag W.O., Lago R.M. and Weisz P.B. (1984). The Active Site of Acidic Aluminosilicate Catalysts. Journal of Nature, 3(1), 589-591.

Karl H.B., Hans-Heinrich M. and Dietmar W. (2008). Industrial inorganic Chemistry. 2nd Completely Revised Edition, John Willey & Sons, Inc., 310-320. IBSN: 978-3- 527-61333-5.

Dyer A. (1988). An Introduction to Zeolite Molecular Sieves. Wiley and Chichester, 14(4), 149-156. ISBN: 0471- 91981-0.

Jiri C., Herman V.B., Avelino C. and Ferdi S. (2007). Introduction to zeolite science and practice. Elsevier, Studies in Surface Science, 2(1), 1058-1065. ISNB: 9780080534794

International Zeolite Association (2010). Zeolite Framework Types. http://izasc.ethz.ch/fmi/xsl/IZASC/ft.xsl, 23/07/2010.

Ruren X.G., Chem J. and Wenfu Y. (2007). From Zeolites to Porous MOF Materials. Elsevier, 1(16), 168-179.

Ye Z. and Yaping X. (2008). Synthesis of pure zeolite from supersaturated silicon and aluminium alkali extract from fuel coal fly ash. Fuel processing technology, 4(32), 56-64.

Auerbach S., Carrado K.A. and Dutta P.K. (2003). Handbook of zeolite science and technology. New York Marcel Decker Inc., 11(7), 10-19.

Zorpas A. and Inglezakis V.J. (2009). Natural Zeolites: Industrial and Environmental Applications Handbook of Zeolites. New York Nova Science Publisher Inc., 1(4), 45- 57.

Downloads

Published

18-09-2024

How to Cite

Kamlesh Sahu. (2024). STUDIES ON THE SYNTHESIS AND CHARACTERIZATION OF ZEOLITES AND THEIR APPLICATION AS A CATALYST. International Journal for Research Publication and Seminar, 15(3), 357–364. Retrieved from https://jrps.shodhsagar.com/index.php/j/article/view/1518